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Substitution For Bittersweet Chocolate . Cocoa powder works well with chocolate cakes, drinks, ice cream, and biscuits. If you need to, bittersweet chocolate substitutions are semi-sweet chocolate or unsweetened cocoa powder. Cacao Barry Mi Amere 58% Bittersweet Chocolate - 5 kg - Cambie (Nicholas Alvarez) By adding the cocoa powder you'll give the baking goods a nice chocolate taste. This will give your recipe the much-needed consistency and texture as that of bittersweet chocolate! Chocolate , Chocolate As mentioned above the answer is no. It will result in a smoother consistency than trying to do it in the microwave. Bittersweet is most commonly used for baking and is perfect for recipes where chocolate is the most prominent flavor. substituting bittersweet chocolate for unsweetened | One Day Café Semi-Sweet Baking Chocolate Substitute